The occupied/emptied sites analysis of Lithium Titanium Oxide anodes : How can we obtain high resolution solid state Lithium NMR spectra?

  • Summary

NM200001E

Lithium ion secondary batteries using spinel-type lithium titanium oxide (LTO) as the negative electrode material are excellent in safety and cycle characteristics due to their chemical stability, and have already been put into practical use. The reaction mechanism of LTO in LIBs well known as the two-phase transition is described as follows.
(Li3)8a(LiTi5)16dO12 + 3Li+ + 3e- ←→ (Li6)16c(LiTi5)16dO12

In order to analyze the sites that are occupied / emptied during Li insertion/removal, it is desirable to distinguish three sites, 8a, 16d and 16c. However, the chemical shifts difference between 8a and 16d sites are very small, and only single signals can be confirmed with a wide line width in the highly sensitive and commonly used 7Li solid-state NMR spectrum as shown in Figure 1a.

6Li MAS NMR

 There are also 6Li atoms that can be observed by NMR. Although the sensitivity is about 1/30 of 7Li due to its smaller natural abundance and magnetic ratio, the smaller quadrupole moment and homonuclear dipolar coupling result in a narrower line width than 7Li. As shown in Figure 1b, the 8a and 16d sites can be distinguished in 6Li solid state NMR spectrum Although the measurement takes time, a typical solid-state NMR sample tube, such as 3.2mm in diameter, can acquire spectra.

6Li

7Li

Natural abundance / %

7

93

Spin

1 3/2

Magnetic ratio / rad s-1 T-1

3.94 x 107

10.4 x 107

Quadrupole moment

-8 x 10-4

-4 x 10-2

The sample is kindly provided by Dr. M. Kitta (AIST)

A part of the spectra in this application note is from a paper in the following.
M. Kitta, T. Kojima, R. Kataoka, K. Yazawa, and K. Tada ACS Appl. Mater. Interfaces 2020, 12, 8, 9322-9331

Please see the PDF file for the additional information.
Another window opens when you click.

PDF 292KB

SEARCH APPLICATIONS

Related Products