Facilities

In November 2014, JEOL collaborated with RIKEN to establish RIKEN CLST-JEOL Collaboration Center. The center serves to create unique technologies for Japan to compete in global competition in the field of analytical/diagnostic instruments.

Publications


[2017]

Book chapter

  • Yusuke Nishiyama, Solid-state NMR under ultrafast MAS rate of 40 – 120 kHz, in Experimental Approaches of NMR Spectroscopy ‐ Methodology and Application to Life Science and Materials Science, Springer.
  • Takeshi Kobayashi, Yusuke Nishiyama, Marek Pruski, Heteronuclear correlation spectroscopy with inverse detection, in Modern Methods in Solid-State NMR: A Practitioner's Guide, Royal Society of Chemistry.

  • [40] Joshua Damron, Kortney Kersten, Manoj Pandey, Kamal Mroue, Jayasubba Reddy, Yusuke Nishiyama, Adam Matzger*, Ayyalusamy Ramamoorthy*, "Electrostatic Constraints Assessed by 1H MAS NMR Illuminate Differences in Crystalline Polymorphs", J. Phys. Chem. Lett., in press.
  • [39] Michal Malon, Manoj Kumar Pandey and Yusuke Nishiyama*, evealing the Local Proton Network Through Three-Dimensional 13C/1H Double Quantum/1H Single Quantum and 1H Double Quantum/13C/1H Single Quantum Correlations Fast MAS Solid-State NMR Spectroscopy at Natural Abundance, J. Phys. Chem. B, in press.
  • [38] Nghia Tuan Duong, Masanori Yamato, Masayuki Nakano, Satoshi Kume, Yasuhisa Tamura, Yosky Kataoka, Alan Wong, Yusuke Nishiyama*, Capillary-inserted rotor design for HRµMAS NMR-based metabolomics on mass-limited neurospheres, Molecules 22 (2017) 1289.
  • [37] Joshua T. Damron, Kortney M. Kersten, Manoj Kumar Pandey, Yusuke Nishiyama, Adam J. Matzgera, Ayyalusamy Ramamoorthy*, Role of Anomalous Water Constraints in the Efficacy of Pharmaceuticals Probed by 1H Solid-State NMR, ChemistrySelect, in press.
  • [36] Xueyan Feng, Ruimeng Zhang, Yiwen Li, You-lee Hong, Dong Guo, Kening Lang, Kuan-Yi Wu, Mingjun Huang, Jialin Mao, Chrys Wesdemiotis, Yusuke Nishiyama, Wei Zhang, Wei Zhang, Toshikazu Miyoshi, Tao Li, Stephen Cheng*, Hierarchical Self-Organization of ABn Dendron-like Molecules into Supramolecular Lattice Sequence, ACS Central, in press.
  • [35] Henri Colaux, Yusuke Nishiyama*, Resolution Enhancement in Proton Double Quantum Magic-Angle Spinning Spectra by Constant-Time Acquisition, Solid State Nucl. Mang. Reson. in press.
  • [34] Rongchun Zhang,† Nghia Tuan Duong,† Yusuke Nishiyama*, Ayyalusamy Ramamoorthy*, 3D Double-Quantum / Double-Quantum Exchange Spectroscopy of Protons Under 100 kHz Magic Angle Spinning, J. Phys. Chem. B. 121 (2017) 5944-5952.
  • [33] Lalit Rajput, Manas Banik, Jayasubba Reddy Yarava, Sumy Joseph, Manoj Kumar Pandey, Yusuke Nishiyama and Gautam R. Desirajua, Exploring the salt-cocrystal continuum with solid-state NMR using natural abundance samples: implications for crystal engineering, IUCrJ 4 (2017) 466-475.
  • [32] Tetsuo Oikawa, Manabu Okumura, Tsunehisa Kimura and Yusuke Nishiyama, Solid-state NMR meets electron diffraction: Determination of crystalline polymorphs of small organic microcrystalline samples, Acta Cryst. C73 (2017) 219–228.
  • [31] Nghia Tuan Duong, Yusuke Nishiyama, Satellite and central transitions selective 1H/{27Al} D-HMQC experiments at very fast MAS for quadrupolar couplings determination, Solid State Nucl. Magn. Reson., 84 (2017) 83-88.
  • [30] Xiaoran Liu, Yuta Makita, You-lee Hong, Yusuke Nishiyama, and Toshikazu Miyoshi, Chemical Reactions and Their Kinetics of Atactic-Polyacrylonitrile As Revealed by Solid-State 13C NMR, macromolecules 50 (2017) 244-253.

[2016]

  • [29] G.N. Manjunatha Reddy, Michal Malon, Andrew Marsh, Yusuke Nishiyama, Steven P. Brown, A fast magic-angle spinning three-dimensional NMR experiment for simultaneously probing H-H and N-H proximities in solids, Analytical Chemistry, 88 (2016) 11412–11419.
  • [28] Manoj K. Pandey, Kenjiro Hashi, Shinobu Ohki, Gen Nishijima, Shinji Matsumoto, Takashi Noguchi, Kenzo Deguchi, Atsushi Goto, Tadashi Shimizu, Hideaki Maeda, Masato Takahashi, Yoshinori Yanagisawa, Toshio Yamazaki, Seiya Iguchi, Ryoji Tanaka, Takahiro Nemoto, Tetsuo Miyamoto, Hiroto Suematsu, Kazuyoshi Saito, Takashi Miki, Yusuke Nishiyama, 24 T High Resolution and Sensitivity Solid-State NMR Measurements of Low-Gamma Half-Integer Quadrupolar Nuclei 35Cl and 37Cl, Analytical Sciences, 32 (2016) 1339-1345.
  • [27] Nghia Duong, Yuki Endo, Takahiro Nemoto, Hiroshi Kato, Anne-Karine Bouzier-Sore, Yusuke Nishiyama, Alan Wong, Evaluation of a high-resolution micro-size magic angle spinning (HRμMAS) probe for NMR-based metabolomic studies of nanolitre samples, Analytical Methods 8 (2016) 6815-6820.
  • [26] Manoj Kumar Pandey, Jean-Paul Amoureux, Tetsuo Asakura, Yusuke Nishiyama, Sensitivity enhanced 14N/14N correlations to probe inter-beta-sheet interactions using fast magic angle spinning solid-state NMR in biological solids, PhysChemChemPhys 18 (2016) 22583-22589.
  • [25] Munehiro Inukai, Satoshi Horike, Tomoya Itakura, Ryota Shinozaki, Naoki Ogiwara, Daiki Umeyama, Sanjog Nagarkar, Yusuke Nishiyama, Michal Malon, Akari Hayashi, Takashi Ohhara, Ryoji Kiyanagi, Susumu Kitagawa, Encapsulating mobile proton carriers into structural defects in coordination polymer crystals: high anhydrous proton conduction and fuel cell application, J. Am. Chem. Soc. 138, 8505-8511.
  • [24] Yusuke Nishiyama, Fast Magic-Angle Sample Spinning Solid-State NMR at 60-100 kHz for Natural Abundance Samples, Solid State Nuclear Magnetic Resonance, 78 (2016) 24-36.
  • [23] Zonghan Hong, Derek Yiren Ong, Subas Kumar Muduli, Pei Chui Too, Guo Hao Chan, Ya Lin Tnay, Shunsuke Chiba, Yusuke Nishiyama, Hajime Hirao, Han Sen Soo, Understanding the Origins of Nucleophilic Hydride Reactivity of a Sodium Hydride–Iodide Composite, Chem. Eur. J., 22 (2016) 7108-7114.
  • [22] Hideaki Maeda, Toshio Yamazaki, Yusuke Nishiyama, Mamoru Hamada, Kenjiro Hashi, Tadashi Shimizu, Hiroto Suematsu, Yoshinori Yanagisawa, Development of Super-high-field NMR Operated Beyond 1 GHz Using High-temperature Superconducting Coils, eMagRes 5 (2016) 1-12.
  • [21] Manoj Kumar Pandey, Jayasubba Reddy Yarava, Rongchun Zhang, Ayyalusamy Ramamoorthy, Yusuke Nishiyama, Proton-detected 3D 15N/1H/1H isotropic/anisotropic/isotropic chemical shift correlation solid-state NMR at 70 kHz MAS, Solid State Nucl. Magn. Reson. 76-77 (2016) 1-6.
  • [20] Manoj Kumar Pandey, Hiroshi Kato, Yuji Ishii, Yusuke Nishiyama, Two-dimensional proton-detected 35Cl/1H correlation solid-state NMR experiment under fast magic angle sample spinning: Application to pharmaceutical compounds, PhysChemChemPhys, 18 (2016) 6209-6216.
  • [19] Y. Nishiyama, M. Malon, M.J. Potrzebowski, P. Paluch, J.P. Amoureux, Accurate NMR determination of C–H or N–H distances for unlabeled molecules, Solid State Nucl. Magn. Reson. 73 (2016) 15-21.
  • [18] Ann-Christin Pöppler, Jean-Philippe Demers, Michal Malon, Amit Pratap Singh, Herbert W. Roesky, Yusuke Nishiyama, Adam Lange, Ultra-fast Magic Angle Spinning: Benefits for the Acquisition of Ultra-wideline NMR Spectra of Heavy Spin-½ Nuclei, ChemPhysChem 17 (2016) 812-816.

[2015]

  • [17] Manoj Kumar Pandey, Yusuke Nishiyama, Determination of NH Proton Chemical Shift Anisotropy with 14N-1H Heteronuclear Decoupling using Ultrafast Magic Angle Spinning Solid-State NMR, J. Magn. Reson. 261 (2015) 133-140.
  • [16] Yusuke Nishiyama, Yuki Endo, Takahiro Nemoto, Anne-Karine Bouzier-Sore, Alan Wong, High resolution NMR-based metabolic detection of microgram biopsies using a 1 mm HRMAS probe, Analyst 140 (2015) 8097-8100.
  • [15] Manoj Kumar Pandey, Rongchun Zhang, Kenjiro Hashi, Shinobu Ohki, Gen Nishijima, Shinji Matsumoto, Takashi Noguchi, Kenzo Deguchi, Atsushi Goto, Tadashi Shimizu, Hideaki Maeda, Masato Takahashi, Yoshinori Yanagisawa, Toshio Yamazaki, Seiya Iguchi, Ryoji Tanaka, Takahiro Nemoto, Tetsuo Miyamoto, Hiroto Suematsu, Kazuyoshi Saito, Takashi Miki, Ayyalusamy Ramamoorthy, and Yusuke Nishiyama, 1020 MHz Single-Channel Proton Fast Magic Angle Spinning Solid-State NMR Spectroscopy, J. Magn. Reson. 261 (2015) 1-5.
  • [14] Rongchun Zhang, Yusuke Nishiyama, and Ayyalusamy Ramamoorthy, Proton-Detected 3D 1H/13C/1H Correlation Experiment for Structural Analysis in Rigid Solids Under Ultrafast-MAS above 60 kHz, J. Chem. Phys. 143 (2015) 164201.
  • [13] Ayesha Wickramasinghe, Songlin Wang, Isamu Matsuda, Yusuke Nishiyama, Takahiro Nemoto, Yuki Endo, Yoshitaka Ishii, Evolution of CPMAS under fast magic-angle-spinning at 100 kHz and beyond, Solid State Nucl. Magn. Reson. 72 (2015) 9-16.
  • [12] Aiden J. Robertsona, Manoj Kumar Pandey, Andrew Marsh, Yusuke Nishiyama, Steven P. Brown, The use of a selective saturation pulse to suppress t1 noise in two-dimensional 1H fast magic angle spinning solid-state NMR spectroscopy, J. Magn. Reson. 260 (2015) 89-97.
  • [11] Songlin Wang, Sudhakar Parthasarathy, Yiling Xiao, Yusuke Nishiyama, Fei Long, Isamu Matsuda, Yuki Endo, Takahiro Nemoto, Kazuo Yamauchi, Tetsuo Asakura, Mitsuhiro Takeda, Tsutomu Terauchi, Masatsune Kainosho, and Yoshitaka Ishii, Nano-mole Scale Sequential Signal Assignment by 1H-Detected Protein Solid-state NMR, Chem. Comm. 51 (2015) 15055-15058.
  • [10] Manoj Kumar Pandey, Yusuke Nishiyama, Proton-detected 3D 14N/14N/1H chemical shift correlation experiment mediated through 1H-1H RFDR mixing on a natural abundant sample under Ultrafast MAS, J. Magn. Reson. 258 (2015) 96-101.
  • [9] Rongchun Zhang, Manoj Kumar Pandey, Yusuke Nishiyama, and Ayyalusamy Ramamoorthy, A Novel High-Resolution and Sensitivity-Enhanced Three-Dimensional Solid-State NMR Experiment Under Ultrafast Magic Angle Spinning Conditions, Scientific Rep. 5 (2015) 11810.
  • [8] Manoj Kumar Pandey, Yusuke Nishiyama, Determination of Relative Orientation between 1H CSA tensors from a 3D Solid-State NMR Experiment mediated through 1H/1H RFDR mixing under Ultrafast MAS, Solid State Nucl. Magn. Reson. 70 (2015) 15-20.
  • [7] Kamal Mroue, Yusuke Nishiyama, Manoj Pandey, Bo Gong, Erin McNerny, David Kohn, Michael Morris, Ayyalusamy Ramamoorthy, Proton-Detected Solid-State NMR Spectroscopy of Bone with Ultrafast Magic Angle Spinning, Scientific Rep. 5 (2015) 11991.
  • [6] Songlin Wang, Sudhakar Parthasarathy, Yusuke Nishiyama, Yuki Endo, Takahiro Nemoto, Kazuo Yamauchi, Tetsuo Asakura, Mitsuhiro Takeda, Tsutomu Terauchi, Masatsune Kainosho, and Yoshitaka Ishii, Nano-mole Scale Side-chain Signal Assignment by 1H-Detected Protein Solid-state NMR by Ultra-Fast Magic-Angle Spinning and Stereo-Array Isotope Labeling, PROS-ONE, 10(4) (2015) e0122714.
  • [5] Yusuke Nishiyama, Takeshi Kobayashi, Michal Malon, Dilini Singappuli-Arachchige, Igor I Slowing, Marek Prsuki, Studies of minute quantities of natural abundance molecules using 2D heteronuclear correlation spectroscopy under 100 kHz MAS, Solid State Nucl. Magn. Reson. 66-67 (2015) 56-61.
  • [4] Piotr Paluch, Julien Trébosc, Yusuke Nishyama, Marek Potrzebowski, Michal Malon, Jean-Paul Amoureux, Theoretical study of CP-VC: a simple, robust and accurate MAS NMR method for analysis of dipolar C-H interactions under rotation speeds faster than ca. 60 kHz, J. Magn. Reson. 252 (2015) 67-77.
  • [3] Rongchun Zhang, Yusuke Nishiyama, Pingchuan Sun, Ayyalusamy Ramamoorthy, Phase Cycling Schemes for finite-pulse-RFDR MAS Solid State NMR Experiments, J. Magn. Reson. 252 (2015) 55-66.
  • [2] Tetsuo Asakura, Takuya Ohata, Shunsuke Kametani, Keiko Okushita, Koji Yazawa, Yusuke Nishiyama, Katsuyuki Nishimura, Akihiko Aoki, Furitsu Suzuki, Hironori Kaji, Anne Ulrich, Mike Williamson, Inter-molecular packing in B. mori silk fibroin: multinuclear NMR study of the model peptide (Ala-Gly)15 defines a heterogeneous anti-parallel anti-polar mode of assembly in the Silk II form, Macromol. 48 (2015) 28-36.
  • [1] Manoj Kumar Pandey, Michal Malon, Ayyalusamy Ramamoorthy, Yusuke Nishiyama, Composite-180° Pulse-Based Symmetry Sequences to Recouple Proton Chemical Shift Anisotropy Tensors under Ultrafast MAS Solid-State NMR Spectroscopy, J. Magn. Reson. 250 (2015) 45-54.