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Radicals generated by pulse laser photo-irradiation have a very short life, so cannot be detected by magnetic field modulation methods. Time-resolved ESR can effect a time-resolution of sub microsecond by direct detection of ESR. Identification of shortlife intermediates generated in the initial stages of chemical reactions may therefore be possible.
Time-resolved system composition figure
TMDPO の時間分解ESR スペクトル
- Wide Band Pre-amplifier (ES-WBPA4)
- Digital oscilloscope
- Time-resolved ESR software
Other essential items : Laser and light path