Degradation of rotary vacuum pump oil determined by field desorption (FD) - TOFMS and group-type analysis software [GC-TOFMS Application]
MSTips No.98
Introduction
Field desorption (FD) is an ionization method in which an electron of the analyte molecule is extracted by tunneling effect under very strong electric field at the surface or at the tips of the "whiskers" grown from the emitter. The analyte is applied as a thin film directly to the emitter and heated by passing a current through the emitter.
FD has been used for the analysis of nonvolatile compounds, synthetic polymers, etc., as a soft ionization method to produce molecular ions with little or no fragmentations.
New and used oil for rotary vane vacuum pump (RP hereafter) were analyzed and the change in their compositions was determined by performing group-type analysis on the FD mass spectra.
Methods
Fig.1 RP oil (left: used, right: new)
Samples: RP oil(new and used)
MS conditions:
Mass spectrometer: JMS-T100GC "AccuTOF™ GC"
Ionization mode: FD(+)
Cathode potential: -10 kV
Emitter current: 0 mA → 51.2 mA/min → 40 mA
Acquired mass range: m/z 35 – 1,600
Spectral recording interval: 0.5 sec
Results and discussion
The acquired FD mass spectra are shown below.
Fig.2 Acquired FD mass spectra
As shown in Fig.2, typical FD mass spectra for hydrocarbon mixture were obtained. Since the difference was rather subtle (more peaks were observed for the new oil at around m/z 500,) group-type analysis was performed to determine the differences in their composition. The results are shown below.
Table 1 Type analysis result of new RP oil
Series Label | Mn | Mw | Mz | PD | DPn | DPw | DPz | Percent Series |
---|---|---|---|---|---|---|---|---|
Total/Average | 453.82 | 483.97 | 531.27 | 1.07 | 25.57 | 27.73 | 31.10 | 100.00 |
CnH2n+2 | 447.44 | 479.98 | 533.06 | 1.07 | 24.78 | 27.10 | 30.89 | 15.47 |
CnH2n | 435.82 | 462.47 | 504.05 | 1.06 | 24.10 | 26.00 | 28.96 | 23.19 |
CnH2n-2 | 451.28 | 482.02 | 530.39 | 1.07 | 25.34 | 27.54 | 30.99 | 16.70 |
CnH2n-4 | 464.22 | 498.14 | 551.19 | 1.07 | 26.41 | 28.83 | 32.61 | 12.69 |
CnH2n-6 | 459.36 | 486.90 | 529.76 | 1.06 | 26.21 | 28.17 | 31.23 | 18.90 |
CnH2n-8 | 478.50 | 511.38 | 561.52 | 1.07 | 27.72 | 30.06 | 33.64 | 13.06 |
Table 2 Type analysis result of used RP oil
Series Label | Mn | Mw | Mz | PD | DPn | DPw | DPz | Percent Series |
---|---|---|---|---|---|---|---|---|
Total/Average | 446.82 | 483.77 | 546.99 | 1.08 | 25.05 | 27.68 | 32.20 | 100.00 |
CnH2n+2 | 434.74 | 473.54 | 544.08 | 1.09 | 23.88 | 26.64 | 31.68 | 16.76 |
CnH2n | 425.93 | 455.81 | 507.39 | 1.07 | 23.39 | 25.52 | 29.20 | 26.43 |
CnH2n-2 | 444.90 | 481.25 | 543.39 | 1.08 | 24.89 | 27.48 | 31.91 | 17.57 |
CnH2n-4 | 461.91 | 506.41 | 581.41 | 1.10 | 26.24 | 29.42 | 34.77 | 12.03 |
CnH2n-6 | 458.94 | 494.97 | 555.72 | 1.08 | 26.18 | 28.75 | 33.08 | 16.65 |
CnH2n-8 | 485.15 | 530.63 | 603.67 | 1.09 | 28.19 | 31.44 | 36.65 | 10.58 |
Hydrocarbon types with different degrees of unsaturation were used.
The hydrocarbon types used were CnH2n+2, CnH2n, CnH2n-2, CnH2n-4, CnH2n-6, and CnH2n-8. The difference in hydrocarbon compositions is shown below.
Table 3 Difference in hydrocarbon compositions
As shown in Table 3, fraction of highly unsaturated hydrocarbons, i.e., CnH2n-4, CnH2n-6, and CnH2n-8, decreased while fraction of moderately unsaturated and saturated hydrocarbons, i.e., CnH2n-2, CnH2n, and CnH2n+2 increased in used RP oil. This suggests either opening of ring structures or hydrogenation of double bonds or triple bonds in CnH2n-4, CnH2n-6, and CnH2n-8.
Another possibility is oxidative degradation of unsaturated hydrocarbons. The exact masses of analysis conditions used. However, the apparent increase of saturated and moderately unsaturated hydrocarbons and decrease of highly unsaturated hydrocarbons could be partly due to the oxidation products.
The difference in compositions of new and used RP oil was clearly revealed by group-type analysis.
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